Conveners
MeV-UED Enabled Ultrafast Chemical Science in Gas and Liquid Phases
- Yusong Liu (SLAC)
Description
Gas and Liquid Phase Chemical Science Enabled by MeV-UED
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Dr Yusong Liu (SLAC, LCLS)8/27/25, 2:00 PM
Provide an introduction to the invited speakers and an overview of the scientific presentations in the session.
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Dr Pedro Nunes (Diamond Light Source, Ltd)8/27/25, 2:05 PM
Gas-phase ultrafast electron diffraction (UED) has become a powerful tool for capturing molecular dynamics with femtosecond temporal and atomic spatial resolutions, enabling direct observation of phenomena such as photo-dissociation, ring-opening reactions, and nuclear wavepacket motion through conical intersections. Despite significant progress, several challenges remain: temporal resolution...
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Prof. Daniel Rolles (Kansas State University)8/27/25, 2:35 PM
The five-member ring isomers oxazole and isoxazole (C3H3NO) are an interesting model system for studying UV-induced isomerization and dissociation since the different types of bonds in both isomers (C-N-C-O vs C-N-O-C) are predicted to lead to very different reaction products and dynamics. I will present time-resolved product yields for both isomers obtained from a recent GUED experiment and...
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Dr Oliver Gessner (LBNL)8/27/25, 3:05 PM
Bromoform (CHBr3) is a natural compound whose UV photodissociation products contribute to ozone depletion in the Earth’s atmosphere. Ultrafast electron diffraction is used to study atomic rearrangements in isolated and in solvated bromoform molecules after 267 nm excitation. The gas phase study provides the first experimental visualization of a long-predicted ultrafast isomerization channel....
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Dr Elisa Biasin8/27/25, 3:40 PM
Femtosecond X-ray solution scattering (XSS) has enabled us to capture photoinduced structural dynamics in solvated transition metal complexes with atomic-scale resolution, revealing intramolecular changes, vibrational coherences, and solvation dynamics. In this talk, I will present recent XSS results from the LCLS, with a particular emphasis on tracking photoinduced solute–solvent...
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Prof. Jie Yang (TsingHua University)8/27/25, 4:10 PM
Laser-induced streaking (LIS) of electron beam, first observed by Zewail group back in 1994, is a unique phenomenon in UED that is often used to conveniently identify time-zero in UED experiments. In the gas phase, LIS originates from plasma field created by strong field ionization of sample molecules, hence named as “photoionization-induced lensing” by Zewail. Separately, LIS can also be...
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Prof. Russell Minns (University of Southampton)
To be determined
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